Due to the unequal distribution of electrons between the sulphur and oxygen atoms, the molecular geometry of the SO2 molecule is twisted or V-shaped, and it is polar.
Three atoms make up the SO2 molecule: one sulphur, two oxygen. The two oxygen atoms are covalently connected to the sulphur atom, which is the centre atom. The configuration of the atoms around the sulphur atom in the middle determines the molecular shape of SO2. The SO2 molecule is bent or twisted because the two oxygen atoms in it are situated on opposing sides of the sulphur atom. A bent or V-shaped molecular geometry is the outcome of this. Because the two S-O bonds' bond dipoles do not cancel out, the molecule as a whole is polar.
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Draw all important contributing structures for the following allylic carbocation. You do not have to consider stereochemistry. Draw all contributing structures in the window below, including the structure given above. Remember that resonance forms which appear to be the same through symmetry are considered to be different resonance forms. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate resonance structures using the doubleheadarrow symbol from the drop-down menu.
The all important contributing structures for the following allylic carbocation is given below image.
Vinylic and allylic carbon atoms are two types of double-bonded carbon atoms. The vinyl group's general formula is R-CH=CH2, where R is placed in the vinylic position and both carbon atoms are joined by a double bond.
The sp3 hybridised carbon atom in the allylic group RCH2-CH=CH2 that is linked to the -CH=CH2 group is the allylic carbon atom.
For instance, the allylic carbon atom (CH3-CH=CH2) is indicated in propene. Similar to this, the allylic carbon atoms close to the double bond in cyclohexene.
Ionic species known as carbocations have a positive charge on the molecule's carbon atom. Typically, they develop as an intermediary during different chemical processes. The steric hindrance and +I impact of the alkyl groups linked to the carbocation's C+ dictate the stability of the compound.
The positively charged carbon atom of the carbocation diminishes the positive charge on the carbocation as the +I effect grows. We may thus conclude that the stability of the carbocation rises along with the amount of alkyl groups on C+.
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what is BEFORE and AFTER when you put the baking soda in vinegar?
When you mix baking soda and vinegar, a chemical reaction occurs that produces carbon dioxide gas, water, and a type of salt called sodium acetate.
What happens at the mixing of baking soda in vinegar?Before: Before mixing baking soda and vinegar, they are both in their separate states. Baking soda is a white powder, and vinegar is a clear liquid.
During: When you mix the baking soda and vinegar, the baking soda (sodium bicarbonate) reacts with the vinegar (acetic acid) to produce carbon dioxide gas (CO2), water (H2O), and sodium acetate (NaC2H3O2).
After: After the chemical reaction has taken place, you will see bubbles of carbon dioxide gas being released. The solution will also become cloudy as the sodium acetate precipitates out. The resulting mixture may feel warmer due to the exothermic nature of the reaction (meaning it releases heat).
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Which of the following will increase the pH of an H2CO3/HCO+3 buffer solution? Removing carbonic acid Adding sodium bicarbonate None of these Both Iand Il II only Ionly
According to the given options, option "II only" will increase the pH of an H2CO3/HCO+3 buffer solution.
Buffer solution- A buffer solution is a solution that resists changes in pH when small amounts of an acid or a base are added to it.
H2CO3/HCO+3 buffer- A buffer that consists of a weak acid and its conjugate base is known as an acid-buffer or a weak acid-buffer. For example, carbonic acid (H2CO3) and bicarbonate (HCO3−) are combined in a buffer solution that has a weak acid (H2CO3) and its conjugate base (HCO3−). Carbonic acid (H2CO3) and bicarbonate (HCO3−) are combined in a buffer solution that has a weak acid (H2CO3) and its conjugate base (HCO3−).
The chemical equation for the carbonic acid-bicarbonate buffer is:
H2CO3 ⇌ H+ + HCO3−
This reaction shows that the buffer solution contains both carbonic acid (H2CO3) and bicarbonate (HCO3−) ions. H+ and HCO3− ions are formed when carbonic acid (H2CO3) dissociates in water (H2O).
Increasing the pH of a buffer solution- The pH of a buffer solution can be increased by adding a strong base, which would react with the buffer's weak acid to form its conjugate base. In this scenario, sodium bicarbonate (NaHCO3) is a strong base.
Therefore, option "II only" is the correct answer.
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0.12 g of magnesium reacted to produce 0.20 g of magnesium oxide.
Calculate the number of moles of oxygen gas (O₂) that reacted.
Relative atomic mass (A): O = 16
Mass of magnesium (Mg) = 0.12 g
Atomic mass of Mg = 24.31 g/mol (from periodic table)
Number of moles of Mg = Mass of Mg / Atomic mass of Mg
= 0.12 g / 24.31 g/mol
= 0.00494 mol
Number of moles of O₂ = Number of moles of MgO produced / 2
= 0.00650 mol / 2
= 0.00325 mol
When 12 g of Mg fully interacts with oxygen, how much MgO is formed?When the experiment is performed without the crucible cover, the magnesium oxide created reacts with any oxygen in the air. When more oxygen reacts with the magnesium, the amount of magnesium oxide generated will be larger than when the experiment was run without a cover on the crucible.
Also, any water vapour or other gases in the air may react with the magnesium oxide, influencing the final product's mass. As a result of the existence of extra reactants in the air, the mass of magnesium oxide formed will change when the crucible is not covered.
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1.choose your dream car
Car year, make and model
2. Car year make model for second car
3. Miles per gallon on the highway for the first car
4.miles per gallon on the highway for second car
5. Balanced equation for the combustion of octane write the coefficients in order
In the picture look please
6. Assume you drive 15,000 miles in one year calculate the number of gallons of gas online your car uses in one year
7.convert gallons to mL( 1 gallon =3785.4mL)
8. Assume you drive the second car 15,000 miles in one year calculate the number of gallons of gas online your car uses In one year
9.convert gallons to mL for the second car (1 gallon = 3785.4mL)
Which are is more efficient in terms of gas use?
Dream car: 2022 Tesla Model S; Second car: 2022 Toyota Camry
If the price of gas is $3.00 per gallon, how much money would you spend on gas in one year for your dream car and the second car?To calculate the amount spent on gas in one year for each car, we need to multiply the number of gallons of gas used in one year by the price per gallon.
For the dream car: 426.9 gallons x $3.00/gallon = $1280.70 spent on gas in one year.
For the second car: 500 gallons x $3.00/gallon = $1500 spent on gas in one year.
Therefore, you would spend $1280.70 on gas for the dream car and $1500 on gas for the second car in one year.
The Tesla Model S is an electric car, so it does not have miles per gallon on the highway.
The Toyota Camry has a highway mpg of 39.
Balanced equation for the combustion of octane: 2C8H18 + 25O2 → 16CO2 + 18H2O
The first car (Tesla Model S) uses no gasoline, so it does not use any gallons of gas in one year.
Converting 1 gallon to mL: 1 gallon = 3785.4 mL
Assuming you drive the Toyota Camry 15,000 miles in one year and get 39 mpg on the highway: 15,000 miles ÷ 39 miles per gallon = 384.6 gallons
Converting gallons to mL: 384.6 gallons x 3785.4 mL/gallon = 1,455,047.64 mL
The second car (Toyota Camry) uses 384.6 gallons of gas in one year.
Converting gallons to mL for the second car: 384.6 gallons x 3785.4 mL/gallon = 1,455,047.64 mL
The Tesla Model S is more efficient in terms of gas use since it uses no gasoline.
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Why can phosphoric acid not be determined by titration with NaOH using either phenolphthalein or methyl orange indicator?
Phosphoric acid cannot be determined by titration with NaOH using either phenolphthalein or methyl orange indicator because of the presence of multiple dissociation stages in the acid. As a result, the equivalence point cannot be determined accurately.
This is due to the fact that the acid has three dissociation stages. Phosphoric acid (H3PO4) is an example of a polyprotic acid, which means that it has more than one hydrogen ion to donate.
The acid undergoes successive ionization to form H2PO4-, HPO42-, and PO43- ions. The stepwise dissociation reactions are as follows: H3PO4(aq) + H2O(l) → H2PO4-(aq) + H3O+(aq)Ka1 = 7.5 × 10-3H2PO4-(aq) + H2O(l) → HPO42-(aq) + H3O+(aq)Ka2 = 6.2 × 10-8HPO42-(aq) + H2O(l) → PO43-(aq) + H3O+(aq)Ka3 = 4.2 × 10-13
As a result, the pH of the solution after each addition of NaOH will change in a series of steps rather than a single sharp change. As a result, it is impossible to determine the exact equivalence point using either phenolphthalein or methyl orange indicator.
Therefore, it is not possible to determine the amount of phosphoric acid in a solution using the titration method with these indicators.
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what is the degree of polymerization of this polymer if the number-average molecular weight is 500000 g/col?
The degree of polymerization of this polymer if the number-average molecular weight is 500000 g/col is 4000.
What is the degree of polymerization?The degree of polymerization (DP) is the number of repeat units in a polymer chain. DP is a useful concept that provides information about the size of the molecule and its physical characteristics. DP is defined as the molecular weight of the polymer divided by the molecular weight of the repeating unit, which is usually determined using an average value. It is denoted as “n”.
What is number-average molecular weight?The number-average molecular weight (Mn) is the average molecular weight of a polymer chain, calculated based on the number of polymer molecules in the sample. Mn is obtained by dividing the total weight of the sample by the total number of molecules in the sample, which is usually determined by light scattering or gel permeation chromatography (GPC). Mn provides information about the average size of a molecule in a sample. It is denoted as “Mn”.
Formula to calculate degree of polymerization
n = molecular weight of the polymer/molecular weight of the repeating unit
Given,
Number-average molecular weight (Mn) = 500000 g/colWeight of repeating unit (W) = ?Degree of polymerization (n) = ?Now we have to find the weight of repeating unit (W) which can be obtained by the formula,
W = Mn / nW = 500000 / nGiven that number-average molecular weight (Mn) = 500000 g/col
By substituting the values in the above formula, we get,W = 500000 / nAt n = 125W = 500000 / 125 = 4000Hence, the degree of polymerization of this polymer if the number-average molecular weight is 500000 g/col is 4000.
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) Predict the product for the following reaction. Assume you have an excess of potassium tert-butoxide. (CH3),COK Br
The potassium tert-butoxide is final product of the reaction is (CH3)3COH.
Why potassium tert-butoxide is (CH3)3COH?
The product for the given reaction is (CH3)3COH.
Reaction: (CH3)3CBr + KOtBu →(CH3)3COH + KBr
Potassium tert-butoxide (KOtBu) is a strong base that can deprotonate hydrogen from (CH3)3COH to form (CH3)3CO-.On the other hand,
(CH3)3CBr is a tertiary halide that can undergo an E2 reaction.
E2 is the abbreviation for bimolecular elimination reactions,
which involve the abstraction of a proton from the adjacent carbon and the removal of the halide anion.
The hydrogen that is abstracted by KOtBu can only come from the carbon that is adjacent to the bromine in (CH3)3CBr, according to Saytzeff's rule, because this is the carbon with the least number of hydrogens.
As a result, an alkene intermediate will be formed.
The KBr salt will be the by-product.
The alkene intermediate, however, is not present in the end product because it is a reactive molecule and quickly reacts with any available hydrogen.
The hydrogen is provided by the KOtBu base.
As a result, the final product of the reaction is (CH3)3COH.
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Diborane, B2H6, is a useful reagent in organic chemistry. One of the several ways it can be prepared is by the following reaction.
2 NaBH4(aq) + H2SO4(aq) 2 H2(g) + Na2SO4(aq) + B2H6(g)
What volume of 0.0865 M H2SO4, in milliliters, should be used to consume completely 1.05 g of NaBH4?
What mass of B2H6 can be obtained?
Answer:
Diborane, B2H6, is a useful reagent in organic chemistry. One of the several ways it can be prepared is by the following reaction 2 NaBH4(aq) H2SO4(aq) 2 H2 (g) + Na2SO4(aq) + B2H6(g) What volume of 0.0915 M H2SO4, in milliliters, should be used to consume completely 1.35 g of NaBH4? mL 200 What mass of B2H6 can be obtained? 0.51
Explanation:
hope its help
Part B Classify each of the following as a Lewis acid or a Lewis base Drag the appropriate items to their respective bins. View Available Hint(s) Reset Help CH:)3N Fe2+ CH:COO CH:OH COz SO3 Lewis acids Lewis bases'
Lewis acids; Fe^3+, SO3, NO2, CO
Lewis base; (CH3)2NH, H^-, Br^-
What Lewis acids and Lewis bases?In chemistry, a Lewis acid is a substance that can accept a pair of electrons (a Lewis base) to form a covalent bond. This concept was introduced by American chemist Gilbert N. Lewis in 1923. A Lewis acid is also defined as an electron pair acceptor, which means that it can form a bond by accepting a pair of electrons from another molecule or ion.
A Lewis base, on the other hand, is a substance that can donate a pair of electrons (a Lewis acid) to form a covalent bond.
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write the overall equation and mechanism for the synthesis of isopentyl acetate. include structures. include all reagents and products but not solvents. g
The overall equation for the synthesis of isopentyl acetate is:
Acetic Anhydride + Isopentyl Alcohol → Isopentyl Acetate + Water
The mechanism for this reaction is as follows:
Step 1: Protonation of the alcohol by the acetic anhydride
Acetic Anhydride + Isopentyl Alcohol → Isopentyl Acetate + Water
Step 2: Deprotonation of the newly formed acetate by the water, producing isopentyl acetate
Acetic Anhydride + Isopentyl Alcohol + Water → Isopentyl Acetate + Acetic Acid
Therefore, the synthesis of isopentyl acetate involves the reaction between acetic anhydride and isopentyl alcohol, followed by the deprotonation of the acetate by water.
Isopentyl acetate is an ester formed from isopentyl alcohol and acetic acid, which is used as a solvent in the production of essential oils and perfumes. In this reaction, the reaction between isopentyl alcohol and acetic acid is catalyzed by sulfuric acid. The mechanism of the reaction can be explained in terms of the Fischer esterification mechanism. The Fischer esterification mechanism is a chemical reaction that occurs between an alcohol and a carboxylic acid to produce an ester. This mechanism involves the attack of the alcohol's oxygen atom on the carboxylic acid's carbonyl carbon atom. The carbonyl oxygen atom, which is double-bonded to the carbonyl carbon atom, is then deprotonated by the acid catalyst, creating an intermediate. The intermediate then undergoes a proton transfer reaction to produce the final product. The overall equation and mechanism for the synthesis of isopentyl acetate are as follows: CH₃COOH + CH₃CH₂CH(CH₃)OH ⇔CH₃COOCH₂CH(CH3)₂ + H₂OIn this reaction, sulfuric acid is used as a catalyst to speed up the reaction rate. The reaction takes place between isopentyl alcohol and acetic acid to produce isopentyl acetate and water.
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which represents the result of mixing equal volumes of 1 m aluminum chloride, 2 m magnesium chloride, and 1 m potassium chloride solution? (each sphere represents 1 mol of ions.)
The result of mixing equal volumes of 1 M aluminum chloride, 2 M magnesium chloride, and 1 M potassium chloride solution is a colorless and odorless solution that contains six ions in equal amounts.
The AlCl3 dissociates into three ions, one Al3+, and three Cl-.The MgCl2 dissociates into three ions, one Mg2+ and two Cl-.The KCl dissociates into two ions, one K+, and one Cl-.As a result, when the aluminum chloride, magnesium chloride, and potassium chloride solutions are mixed in equal volumes, a total of six ions are present, consisting of one Al3+, one Mg2+, one K+, and three Cl- ions. The composition of the solution, which has six ions in equal amounts, is as follows:
Al3+ (aq) + Mg2+ (aq) + K+ (aq) + 3Cl- (aq) → colorless, odorless solution.
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Reduction involves the ____ of electron(s), and reactions for which the standard cell potential is ____ are spontaneous under standard conditions.
A. loss; negative
B. loss; positive
C. gain; negative
D. gain; positive
E. none of the above
Reduction involves the gain of electrons, and reactions for which the standard cell potential is negative are spontaneous under standard conditions.
Reduction- In a chemical reaction, the process of gaining one or more electrons is known as reduction. It is the opposite of oxidation, which is the loss of electrons in a reaction.
Reduction is the method of reducing the oxidation state of a substance. The reduction of carbon dioxide to glucose during photosynthesis is an example of a biological reduction. The reduction of iron oxides into elemental iron during the blast furnace process is an example of an industrial reduction.
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Calculate the volume of distilled water that should be added to 25cm³ of a 0.125moldm-³ HCL in order to dilute it 10 times, calculate the volume of the added water
Answer:
Explanation:
The volume of distilled water that should be added to 25 cm3 of 0.125 moldm-3 HCl in order to dilute it 10 times can be calculated using the following equation:
Volume of added water = (25 cm3 x 10) / (0.125 moldm-3)
= 200 cm3
Therefore, the volume of distilled water that should be added to 25 cm3 of 0.125 moldm-3 HCl in order to dilute it 10 times is 200 cm3.
draw a lewis structure for ammonia, nh3 . include all hydrogen atoms and show all unshared pairs and the formal charges, if any. assume that bonding follows the octet rule.
The lewis structure for ammonia NH₃ is:
H
|
: N - H
|
H
And there are no formal charges.
Lewis structure for ammoniaTo draw the Lewis structure for NH₃, follow these steps:
1. Determine the total number of valence electrons: Nitrogen (N) has 5 valence electrons, and each Hydrogen (H) atom has 1 valence electron. Since there are 3 Hydrogen atoms, the total valence electrons are 5 + (3 * 1) = 8.
2. Identify the central atom: Nitrogen is the central atom because it has the highest bonding capacity (it can form 3 bonds).
3. Place the central atom and surround it with Hydrogen atoms: Write the symbol for Nitrogen and place the 3 Hydrogen atoms around it in a trigonal planar arrangement.
H
|
H - N - H
4. Connect the atoms with single bonds: Create a single bond between Nitrogen and each Hydrogen atom by placing a pair of electrons (a line) between them. This uses 6 valence electrons (2 for each bond).
5. Distribute the remaining valence electrons: We have used 6 valence electrons so far, and there are 2 more left. Place the remaining 2 electrons as a lone pair on the central Nitrogen atom.
H
|
: N - H
|
H
6. Check the octet rule: Each Hydrogen atom has 2 electrons (1 bond), and Nitrogen has 8 electrons (3 bonds and 1 lone pair). All atoms satisfy the octet rule.
7. Determine formal charges: In NH₃, there are no formal charges, as each atom has the same number of valence electrons as in its neutral state.
The Lewis structure for NH₃ is now complete.
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A neutralization reaction produces H2O and LiNO3. Select the acid-base reactants for this neutralization reaction.
Group of answer choices
a. LiOH
b. HNO
c. LiNO
d. HNO3
e. HLi
The acid-base reactants in this neutralization reaction are (a) LiOH and (d) HNO₃. LiOH is the base in this reaction and HNO₃ is the acid.
A neutralization reaction is a type of chemical reaction in which an acid and a base react to form a salt and water, with the water molecule (H₂O) released as a byproduct. The chemical reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH) is an example of a neutralization reaction.
HCl + NaOH → NaCl + H₂O
For this reaction, hydrochloric acid and sodium hydroxide are acid-base reactants. Sodium chloride is a salt produced by the reaction, and water is produced as a byproduct.
The acid-base reactants for the neutralization reaction that produces H₂O and LiNO₃ are LiOH and HNO₃.
LiOH + HNO₃ → LiNO₃ + H₂O
Lithium hydroxide (LiOH) is a strong base, and nitric acid (HNO₃) is a strong acid. They react to form lithium nitrate (LiNO₃) and water (H₂O), which is a neutral solution.
Therefore, the acid and base in the neutralization reaction that produces H₂O and LiNO₃ are HNO₃ and LiOH respectively.
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Why are carboxylic acids more acidic than water or ethyl alcohol esters?
Carboxylic acids are more acidic than water or ethyl alcohol esters due to their stronger resonance stabilization. Carboxylic acids contain a carboxyl group (COOH) that is able to stabilize the extra electron density of the conjugate base (COO-) through resonance. The more electron-withdrawing atoms in the carboxyl group, the more stable the resonance structure and therefore the stronger the acid. Water and ethyl alcohol esters, on the other hand, have less electron-withdrawing atoms, so their conjugate base is not as stable and their acidity is less than that of carboxylic acids.
Additionally, carboxylic acids tend to have smaller molecules than water or ethyl alcohol esters. This means that their conjugate base will have a stronger interaction with the proton and therefore the acid is stronger. In contrast, water and ethyl alcohol esters are larger molecules and their conjugate base is less capable of stabilizing the proton and thus making the acid less acidic.
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Please help with these 2 questions
Question 1
The enthalpy of vaporization for methanol is 35.2 kJ/mol. Methanol has a vapor pressure of 1 atm at 64.7 °C. Using the Clausius-Clapeyron equation, what is the vapor pressure for methanol at 53.7 °C?
-Give your answer in atmospheres, to the third decimal point.
Question 2
The enthalpy of vaporization for dimethyl ether is 27.5 kJ/mol. Dimethyl ether has a vapor pressure of 760 torr at 34.6 °C. Using the Clausius-Clapeyron equation, what is the vapor pressure for methanol at -14.5 °C? Give your answer in torr, to the first decimal point.
Answer:
Answer 1
2.115 atm
Answer 2
17.9 torr
An atom has eight protons, ten neutrons, and eight electrons. What is the mass number of this atom?a. 10b. 18c. 26d. More information must be given before the mass number can be calculated for the atom.
The total number of protons and neutrons in an atom's nucleus is the atom's mass number. The atom in question contains 8 protons and 10 neutrons, making its mass number:
mass number equals the sum of the protons and neutrons.
number of mass = 8 + 10
total mass = 18
Hence, the response is (b) 18.
The total number of protons and neutrons in an atom's nucleus is the atom's mass number. The atom in the example contains 8 protons and 10 neutrons, therefore combining these two numbers yields the atom's mass number. Hence, this atom has a mass number of 18. It is significant to note that because electrons have a low mass, the number of electrons in an atom has no bearing on the number of protons. For determining which isotopes of an element have the same number of protons but different numbers of neutrons, the mass number is a relevant metric. It's critical to know the mass number when calculating an element's atomic mass, which is the weighted average of the masses.
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Cattails in swamps are used to absorb chemical pollutants. what method of reducing pollutant concentration is this
Phytoremediation is a cost-effective and environmentally friendly method of reducing pollutant concentrations and restoring contaminated ecosystems.
What is Pollutants?
Pollutants are substances or agents that contaminate the environment and have harmful effects on living organisms, natural resources, or the climate. Pollutants can be released into the air, water, or soil from natural sources or human activities such as industrial processes, transportation, agriculture, and waste disposal. Some common examples of pollutants include greenhouse gases, particulate matter, ozone, nitrogen oxides, sulfur dioxide, lead, mercury, pesticides, and plastic waste.
The method of using cattails in swamps to absorb chemical pollutants is called phytoremediation. Phytoremediation is a type of bioremediation that uses plants to remove, detoxify, or sequester contaminants from soil, water, or air. In this process, plants absorb contaminants through their roots or take them up from the air and store them in their tissues or metabolize them into less harmful forms. Cattails are particularly effective at removing organic pollutants such as pesticides, herbicides, and petroleum products, as well as heavy metals like lead, cadmium, and arsenic.
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2. Convert 3 moles of Ba(NO3)₂ to grams of Ba(NO3)2
Answer:
Explanation:
n = m / Mr
Atomic Mass :
Ba =137 ,327
N = 14,0067
O =15,9994
Mr[(Ba(NO3)2] = 137,327 + (14,0067+15,9994*3)*2 = 261,3368 g/mol
so for finding m[Ba(NO3)2] will take :
n = m / Mr
m = n * Mr
m =3 moles * 261,3368 g/moles
m = 784,01 grams
the esterification of acetic acid and ethanol is given by the reaction below:C2H5OH(aq) + CH3COOH(aq) = CH3COOC2H5(aq) + H2OWhen 1.00 mol of ethanol was mixed with 2.00 mol of acid in a 1.00 L flask, 0.86 mol of ester was formed at room temperature. What is the value of the equilibrium constant, Kc?
The value of the equilibrium constant, Kc for the esterification of acetic acid and ethanol is 4.94 x 10⁻².
Esterification is a chemical reaction between a carboxylic acid and an alcohol which leads to the formation of ester as the reaction product. In the presence of a strong acid catalyst, acetic acid reacts with ethanol to form ethyl acetate, an ester, as well as water. The equation of the reaction is:-
C2H5OH(aq) + CH3COOH(aq) ⇌ CH3COOC2H5(aq) + H2O
In this equation, the forward reaction is the esterification of acetic acid and ethanol, while the backward reaction is the hydrolysis of ethyl acetate. The value of the equilibrium constant, Kc, is given by the following equation:-
Kc = [CH3COOC2H5] / [C2H5OH] [CH3COOH]
Substituting the given values into the equation for Kc gives:-
Kc = [0.86] / [1.00] [2.00] = 0.43 / 4 = 0.1085 = 4.94 x 10⁻²
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At what Celsius temperature will argon have a density of 10.3 g/L and a pressure of 6.43 atm?
(31 deg. C)
At 31.52° Celsius temperature will argon have a density of 10.3 g/L and a pressure of 6.43 atm . This is given by ideal gas law.
What is ideal gas ?An ideal gas is a theoretical gas composed of many randomly moving point particles that do not interact with one another. The ideal gas concept is useful because it obeys the ideal gas law, which is a simplified equation of state, and is amenable to statistical mechanics analysis. The requirement of zero interaction is frequently relaxed if the interaction is perfectly elastic or regarded as point-like collisions, for example. When intermolecular forces and molecular size become important, the ideal gas model tends to fail at lower temperatures or higher pressures. It also fails for most heavy gases, including many refrigerants,[2] as well as gases with strong intermolecular forces, most notably water vapor. At high pressures, the volume of a real gas is frequently much larger than that of a pure gas.
using the formula
P × M = d × R × T
Where P = pressure = 6.43 atm
m= molar mass = 40 g
d = density = 10.3 g/L
T = temperature
R = 0.082057 L atm K⁻¹ mol⁻¹
solving for T ,
T = 31.52°C
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1) The (R) enantiomer of a new cancer drug has a specific rotation of +80 deg.
a) what is the specific rotation of the (S) enantiomer? (1 pt)
b) What is the enantiomeric excess of a sample with an observed specific rotation of +40 deg.? (1 pt)
2) How are the molecules below related? Identical, diastereomers, enantiomers, constitutional isomers (1 pt ea; 2 pts total)
3. Determine the degree of substitution for each alkene: monosubstituted, di-, tri-, tetra- (1 pt ea; 2 pts total)
4. Draw curved arrows to show the movement of the electrons that result in the formation of the given product (2 pts total).
5. Indicate the most stable and the least stable alkene in each set (1 pt each, 2 pts total).
1)(a)The (S) enantiomer of a new cancer drug has a specific rotation of -80 deg. b) The enantiomeric excess of a sample with an observed specific rotation of +40 deg. is 40%.
2) The molecules are identical.
3) The degree of substitution for each alkene is monosubstituted, disubstituted, trisubstituted and tetrasubstituted respectively.
4) Curved arrows can be used to show the movement of the electrons that result in the formation of the given product.
5) The most stable alkene in each set is the one with the least number of substituents, and the least stable alkene is the one with the most number of substituents.
1a) The (S) enantiomer of the drug will have a specific rotation of -80 degrees. This is because the (R) and (S) enantiomers are mirror images of each other, and they rotate plane-polarized light in opposite directions.1b) The enantiomeric excess (ee) of a sample with an observed specific rotation of +40 degrees can be calculated using the formula:
ee = (observed rotation/rotation of pure enantiomer) x 100%.
If the drug exists as a single enantiomer, then its specific rotation would be +80 degrees.
Using the formula, ee = (+40/+80) x 100% = 50%.
This means that the sample is a 50:50 mixture of both enantiomers.
2) The relationships between molecules can be summarized as follows: identical molecules are the same and have the same properties; diastereomers are stereoisomers that are not mirror images of each other; enantiomers are stereoisomers that are mirror images of each other; and constitutional isomers have the same molecular formula but different connectivity of atoms.
3) Degree of substitution refers to the number of substituents (groups) on an alkene carbon. A monosubstituted alkene has one substituent, a disubstituted alkene has two substituents, a trisubstituted alkene has three substituents, and a tetrasubstituted alkene has four substituents.
4) To show the movement of electrons that result in the formation of a product, curved arrows are used to show the flow of electrons from a bond or a lone pair to a new bond or a new atom.
5) The most stable alkene is the one that has more substituted carbons, while the least stable alkene has fewer substituted carbons. For example, a tetrasubstituted alkene is more stable than a trisubstituted alkene, which is more stable than a disubstituted alkene, which is more stable than a monosubstituted alkene.
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silver nitrate can inhibit the amylase reaction by?
By severing disfluid connections, silver nitrate can prevent the amylase reaction from happening. Wheat flour's -amylase can be prevented from working by adding silver nitrate (AgNO₃).
As silver nitrate is a non-competitive inhibitor that disrupts the folding of the enzyme, it should be the most efficient in inhibiting amylase at 37°C if different inhibitors are tried with amylase to quantify the quantities of free-reducing sugars.
Accurate evaluation of the pasting qualities of wheat flour is hampered by endogenous -amylase. When rice flour with a medium to high amylose content is gelatinized, the capacity of silver nitrate (AgNO₃) solutions at seven various concentrations (0.001-0.1 m) to inhibit -amylase activity is compared with a deionized water (dH₂O) control (AC). Using a Quick Visco Analyzer, pasting characteristics are evaluated (RVA).
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hydrochloric acid series concentration conductivit y sodium hydroxide 1.0 m sodium hydroxide 0.10 m sodium hydroxide 0.01 m sodium hydroxide 0.001m sodium hydroxide 0.0001m sodium hydroxide 0.00001m measure the conductivity of the acetic acid series and answer the question based on the observed conductivity values. acetic acid series concentration conductivit y acetic acid 17.0 m acetic acid 15.0 m acetic acid 13.0 m acetic acid 11.0 m acetic acid 9.0 m acetic acid 7.0 m acetic acid 3.0 m acetic acid 1.0 m ions responsible for conductivity: transition from strong to weak conductor occurs at: ions responsible for conductivity: transition from strong to weak conductor occurs at:
The ions responsible for conductivity are H+ and OH-, respectively. A transition from a strong to a weak conductor occurs at 1.0M of acetic acid.
Let's start by discussing the conductivity of hydrochloric acid series concentration.
Hydrochloric acid, a strong acid, ionizes completely in water to generate hydrogen ions (H+) and chloride ions (Cl-). Hydrochloric acid is a strong conductor of electricity due to its high ion concentration.
Sodium hydroxide is a strong alkali that completely ionizes in water to form hydroxide ions (OH-). Sodium hydroxide is a strong conductor of electricity due to its high ion concentration.
Acetic acid is a weak acid, which means it does not ionize completely in water. Its ion concentration is reduced as its concentration is decreased, and as a result, it becomes a weaker conductor of electricity. This is because it has fewer ions as its concentration decreases.
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what is the correct order of the five para substituents on the carbocation intermediate, if arranged from most stabilizing to least stabilizing?
The correct order of the five para substituents on the carbocation intermediate, if arranged from most stabilizing to least stabilizing is as follows:1) Methoxy group (-OCH3): Methoxy group is an electron-donating group that has a stabilizing effect on carbocation.2) Alkyl groups (-CH3, -C2H5).
These groups also have an electron-donating effect, but their effect is less than that of methoxy.3) Halogens (-F, -Cl, -Br, -I): These are electron-withdrawing groups, but their inductive effect is much weaker than their mesomeric effect. The mesomeric effect of halogens is electron-donating, which compensates for their inductive electron-withdrawing effect.4) Nitro group (-NO2): Nitro is a strongly electron-withdrawing group that destabilizes carbocation.5) Carbonyl group (-COCH3): Carbonyl is also an electron-withdrawing group that destabilizes carbocation.
They are formed by the loss of a leaving group from a substrate, leaving behind a positively charged carbon atom. The stability of the carbocation intermediate is influenced by the nature of the substituents attached to the carbon atom. Substituents can be electron-donating or electron-withdrawing, depending on their effect on the carbocation.The most stabilizing substituents are electron-donating groups, such as methoxy (-OCH3) and alkyl groups (-CH3, -C2H5). These groups donate electrons to the carbocation, which increases its stability. Halogens (-F, -Cl, -Br, -I) are also electron-donating, but their mesomeric effect is stronger than their inductive effect. This means that their overall effect is electron-donating, but weaker than that of methoxy and alkyl groups.
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Calculate the amount of heat needed to boil 132.g of water (H20), beginning from a temperature of 7.4 °C. Round your answer to 3 significant digits. Also, be sure your answer contains a unit symbol
The amount of heat needed to boil 132 g of water ([tex]H_{2} O[/tex]), beginning from a temperature of 7.4 °C, is 298 kJ.
The amount of heat needed to boil water can be calculated using the following equation:
Q = m * ΔH
Where Q is the amount of heat required, m is the mass of the water, and ΔH is the heat of vaporization of water, which is 40.7 kJ/mol.
First, we need to determine the number of moles of water in 132 g of water:
n = m / M
where M is the molar mass of water, which is approximately 18.015 g/mol.
n = 132 g / 18.015 g/mol = 7.326 mol
Now we can calculate the amount of heat required to vaporize this amount of water:
Q = n * ΔH
Q = 7.326 mol * 40.7 kJ/mol = 298 kJ
Therefore, the amount of heat needed to boil 132 g of water starting from a temperature of 7.4 °C is 298 kJ.
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how would the electron configuration of nitrogen change to make a stable configuration? (1 point) responses it would lose four electrons. it would lose four electrons. it would gain two electrons. it would gain two electrons. it would gain three electrons. it would gain three electrons. it would lose five electrons. it would lose five electrons.
The electron configuration of nitrogen change to make a stable configuration c. it would gain three electrons
Electron configuration is the arrangement of electrons in an atom or molecule. This arrangement is based on the principles of quantum mechanics. It determines how atoms interact with each other, which in turn determines the properties of matter.
The electron configuration of nitrogen is 1s² 2s² 2p³. Nitrogen has five valence electrons, three of which are paired in the 2p orbital, while the other two are in the 2s orbital.Nitrogen has an unstable configuration because it needs three more electrons to complete its valence shell, which can be achieved by gaining three electrons. Therefore, the electron configuration of nitrogen would change to make a stable configuration by gaining three electrons.
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Complete and balance the equation for the single displacement reaction between sodium and aluminum chloride. Phases are optional.
balanced equation: Na(s)+AlCl3(aq)⟶
The aluminum chloride and sodium chloride are dissolved in water as aqueous solutions
Why aluminum and sodium chloride react with each other?
The balanced equation for the single displacement reaction between sodium and aluminum chloride is as follows:
Na(s) + AlCl3(aq) → Al(s) + NaCl(aq)
This is a single displacement reaction because sodium is displacing aluminum from its compound aluminum chloride. The products of the reaction are aluminum and sodium chloride.
The equation balanced is because there are equal numbers of atoms each element on both sides of the equation. The coefficients in front of each molecule indicate the number of molecules of each compound or element that are involved in the reaction.
Na(s) + AlCl3(aq) → Al(s) + NaCl(aq) Phases are optional in the equation, but they can be included to indicate the physical state of each substance.
In this equation,
(s) indicates that sodium is a solid,
(aq) indicates that aluminum chloride and sodium chloride are dissolved in water as aqueous solutions,
and (s) indicates that aluminum is also a solid.
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