The percent yield of the reaction is 87.7%.
So, the correct answer is D.
To determine the percent yield of the reaction between Na and excess Br₂, we need to compare the actual yield to the theoretical yield.
The balanced equation shows that 2 moles of Na react with 1 mole of Br₂ to form 2 moles of NaBr.
We can use this information to calculate the theoretical yield of NaBr from 2.50 g of Na.
First, we need to convert 2.50 g of Na to moles using its molar mass (22.99 g/mol).
This gives us 0.109 moles of Na. Since 2 moles of Na are needed to produce 2 moles of NaBr, we can calculate the theoretical yield of NaBr as 0.109 x 102.89 g/mol = 11.20 g.
The actual yield obtained in the reaction was 9.82 g of NaBr.
Therefore, the percent yield can be calculated as (9.82 g / 11.20 g) x 100% = 87.7% ( Option D)
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What is the pH?
Show work
100. 0 mL of 0. 10 F H3PO4 is mixed with 200. 0 mL 0. 15 M NaOH.
250. 0 mL of 0. 10 M HA (Ka = 1. 0 x 10-4) is mixed with 100. 0 mL 0. 25 M KOH.
100. 0mLof0. 10MHA(Ka =1. 0x10-4)ismixedwith100. 0mLof 0. 050 M NaA
The pH of 100.0 mL of 0.10 M H₃PO₄ is mixed with 200.0 mL of 0.15 M NaOH is 1.00.
a) To determine the pH of the resulting solution, we need to calculate the concentration of the hydronium ion (H₃O⁺) using the concept of acid-base neutralization. The balanced equation for the reaction between H₃PO₄ and NaOH is:
H₃PO₄ + 3NaOH → Na₃PO₄ + 3H₂O
Since H₃PO₄ is a triprotic acid, we can assume that it completely dissociates in water. Therefore, the moles of H₃PO₄ can be calculated as follows:
Moles of H₃PO₄ = (0.10 mol/L) × (0.100 L) = 0.010 mol
To find the concentration of H₃O⁺, we need to consider the stoichiometry of the reaction. In the balanced equation, we see that for every mole of H₃PO₄, three moles of H₃O⁺ are produced. Therefore, the concentration of H₃O⁺ in the resulting solution is:
[H₃O⁺] = (3 × 0.010 mol) / (0.100 L + 0.200 L) = 0.030 mol / 0.300 L = 0.10 M
The pH can be calculated using the formula: pH = -log[H₃O⁺]
pH = -log(0.10) ≈ 1.00
Therefore, the pH of the resulting solution is approximately 1.00.
b) To determine the pH of the resulting solution, we need to consider the reaction between the weak acid (HA) and the strong base (KOH). The balanced equation for this reaction is:
HA + KOH → K⁺ + A⁻ + H₂O
Since HA is a weak acid, it will only partially dissociate in water. We need to consider the initial concentration of HA, the amount of KOH added, and the resulting volume of the solution.
First, let's calculate the moles of HA:
Moles of HA = (0.10 mol/L) × (0.250 L) = 0.025 mol
Next, let's calculate the moles of KOH:
Moles of KOH = (0.25 mol/L) × (0.100 L) = 0.025 mol
Since the moles of KOH are equal to the moles of HA, they will react completely in a 1:1 ratio, resulting in the formation of the potassium salt (K⁺A⁻) and water (H₂O).
The total volume of the resulting solution is the sum of the volumes of HA and KOH:
Total volume = 250.0 mL + 100.0 mL = 350.0 mL = 0.350 L
To determine the concentration of the resulting solution, we divide the moles of the species formed by the total volume:
Concentration of K⁺A⁻ = (0.025 mol) / (0.350 L) ≈ 0.0714 M
Since we have a salt in the solution, we can assume complete dissociation of the salt into its respective ions. Therefore, the concentration of the hydronium ion (H₃O⁺) will be equal to the concentration of the hydroxide ion (OH⁻) due to the neutralization reaction.
Now, let's calculate the concentration of H₃O⁺:
[H₃O⁺] = [OH⁻] = 0.0714 M
Finally, we can calculate the pH using the formula: pH = -log[H₃O⁺]:
pH = -log(0.0714) ≈ 1.15
Therefore, the pH of the resulting solution is approximately 1.15.
c) To determine the pH of the resulting solution, we need to consider the reaction between the weak acid (HA) and the weak base (A⁻). The balanced equation for this reaction is:
HA + A⁻ ⇌ H₂A
Since HA is a weak acid with a given Kₐ value, we can assume that it partially dissociates in water. The initial concentrations of HA and A⁻, as well as the resulting volume of the solution, are given.
First, let's calculate the moles of HA:
Moles of HA = (0.10 mol/L) × (0.100 L) = 0.010 mol
Next, let's calculate the moles of A⁻:
Moles of A⁻ = (0.050 mol/L) × (0.100 L) = 0.005 mol
Now, let's determine the concentrations of HA and A⁻ in the resulting solution:
[H₃A] = (moles of HA) / (total volume) = 0.010 mol / (0.100 L + 0.100 L) = 0.050 M
[HA] = (moles of A⁻) / (total volume) = 0.005 mol / (0.100 L + 0.100 L) = 0.025 M
Since HA and A⁻ have a 1:1 stoichiometric ratio, the concentrations of H₃A and HA are the same in the resulting solution.
To determine the concentration of the hydronium ion (H₃O⁺), we need to consider the dissociation of HA. The Kₐ expression for HA is:
Kₐ = [H₃O⁺] [A⁻] / [HA]
Given that Kₐ = 1.0 x 10⁻⁴ and the concentration of A⁻ is equal to the concentration of H₃A, we can rewrite the equation as:
(1.0 x 10⁻⁴) = (x)² / (0.025)
Solving for x (the concentration of H₃O⁺), we find:
x = √(1.0 x 10⁻⁴) × √(0.025) ≈ 0.0032 M
Now, we can calculate the pH using the formula: pH = -log[H₃O⁺]:
pH = -log(0.0032) ≈ 2.5
Therefore, the pH of the resulting solution is approximately 2.5.
The correct question is :
What is the pH?
100.0 mL of 0.10 M H₃PO₄ is mixed with 200.0 mL of 0.15 M NaOH.
250.0 mL of 0.10 M HA (Kₐ = 1. 0 x 10⁻⁴) is mixed with 100.0 mL of 0.25 M KOH.
100.0 mL of 0. 10 M HA (Kₐ =1. 0x10⁻⁴) is mixed with 100.0 mLof 0.050 M NaA
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What is the molar solubility of BaF2 in 0.30 m Naf? (ksp of baf2 = 1.0 x 10^−6)
The molar solubility of BaF2 in 0.30 M NaF is 6.97 x 10^-4 M.
The solubility of BaF2 in 0.30 M NaF can be calculated using the common ion effect.
When a salt with low solubility, such as BaF2, is added to a solution containing a common ion (in this case, F^- from NaF), the solubility of the salt is reduced due to the Le Chatelier's principle.
The balanced chemical equation for the dissociation of BaF2 is:
BaF2 (s) ↔ Ba2+ (aq) + 2F^- (aq)
The solubility product constant (Ksp) expression for BaF2 is:
Ksp = [Ba2+][F^-]^2
At equilibrium, the concentration of Ba2+ ions in solution is equal to the molar solubility of BaF2, which we can denote as x. Therefore, the concentration of F^- ions in solution is 0.30 M + 2x (due to the dissociation of NaF and the dissociation of BaF2). Substituting these values into the Ksp expression, we get:
1.0 x 10^-6 = x(0.30 M + 2x)^2
Solving this equation for x using the quadratic formula gives:
x = 6.97 x 10^-4 M
Therefore, the molar solubility of BaF2 in 0.30 M NaF is 6.97 x 10^-4 M.
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Sufficient strong acid is added to a solution containing na2hp04 to neutrahze one-half of it. what wul be the ph of this solution?
The chemical formula for sodium dihydrogen phosphate is Na₂HPO₄. When Na₂HPO₄ dissolves in water, it undergoes a hydrolysis reaction and produces H3O⁺ and HPO₄⁻² ions:
Na₂HPO₄ + H₂O → 2 Na⁺ + H3O⁺ + HPO₄⁻²
HPO₄⁻² can act as both an acid and a base. In water, it can donate a proton to water to form H2PO4- and OH-:
HPO₄²⁻ + H₂O ↔ H₂PO₄⁻ + OH⁻
It can also accept a proton from water to form H₂PO₄⁻ and H3O⁺:
HPO₄²⁻ + H₂O ↔ H₂PO₄⁻ + H₃O⁺
When a sufficient amount of strong acid is added to the solution containing Na₂HPO₄ to neutralize one-half of it, it means that half of the HPO₄²⁻ ions have reacted with the added acid and have been converted to H₂PO₄⁻ ions.The other half of the HPO₄²⁻ ions are still present in the solution.
The reaction between HPO₄²⁻ and a strong acid, such as HCl, is:
HPO₄²⁻ + HCl → H₂PO₄⁻ + Cl⁻
The HPO₄²⁻ ions that react with the added acid will no longer be able to act as either an acid or a base, and the remaining HPO₄²⁻ ions will act as a weak base. Therefore, the pH of the solution will depend on the dissociation constant of HPO₄²⁻ as a base.
The dissociation constant of HPO₄²⁻ as a base is given by:
[tex]K_b=k_w/k_a[/tex]
where [tex]K_w[/tex] is the base dissociation constant, [tex]K_w[/tex] is the ion product constant of water (1.0 x 10^-14 at 25°C), and [tex]K_a[/tex] is the acid dissociation constant of H2PO₄²⁻ (6.2 x 10^-8 at 25°C).
Substituting the values, we get:
[tex]K_b=K _w/K _a[/tex]= (1.0 x 10^-14)/(6.2 x 10^-8) = 1.6 x 10^-7
The base ionization constant expression for HPO₄²⁻ is:
[tex]K_b[/tex] = [HPO₄²⁻][OH⁻]/[H₂PO₄²⁻]
At half-neutralization, the concentration of HPO₄²⁻ ions remaining in solution is equal to the initial concentration of Na₂HPO₄ divided by 2. Let's assume that the initial concentration of Na₂HPO₄ is C.
Therefore, the concentration of HPO₄²⁻ ions remaining in solution after half-neutralization is C/2.
At equilibrium, the concentration of H₂PO₄⁻ ions is also C/2, and the concentration of OH⁻ ions can be calculated using the Kb expression:
[tex]K_b[/tex] = [HPO₄²⁻][OH⁻]/[H₂PO₄⁻]
1.6 x 10⁻⁷= (C/2)(OH⁻)/(C/2)
OH⁻ = 1.6 x 10⁻⁷ M
The pH of the solution can be calculated using the relation:
pH = 14 - pOH
pOH = -log[OH⁻] = -log(1.6 x 10⁻⁷) = 6.8
pH = 14 - 6.8 = 7.2
Therefore, the pH of the solution will be 7.2 after sufficient strong acid is added to a solution containing Na₂HPO₄ to neutralize one-half of it.
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how many molecules are present in 4.25 mol of ccl4?
2.559 x 10^24 molecules present in 4.25 mol of CCl4.
To determine how many molecules are present in 4.25 mol of CCl4, you will need to use Avogadro's number.
Here are the steps:
1. Recall that Avogadro's number is 6.022 x 10^23, which represents the number of molecules in one mole of a substance.
2. Multiply the given amount of moles (4.25 mol) by Avogadro's number.
Calculation:
(4.25 mol) x (6.022 x 10^23 molecules/mol) = 2.559 x 10^24 molecules
So, there are 2.559 x 10^24 molecules present in 4.25 mol of CCl4.
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how many chlorine atoms are in 23 molecules of phosphorus pentachloride, pcl₅?
In 23 molecule of phosphorus pentachloride there are 115 Chlorine atoms.
There are 115 chlorine atoms in 23 molecules of phosphorus pentachloride, PCl₅. This is because each molecule of PCl₅ contains 5 chlorine atoms, and since there are 23 molecules, we can simply multiply 5 by 23 to get 115.
Phosphorus pentachloride, PCl₅, is a covalent compound that is composed of one phosphorus atom and five chlorine atoms. The prefix "penta" means five, which tells us that there are five chlorine atoms in each molecule of PCl₅. To determine the total number of chlorine atoms in 23 molecules of PCl₅, we can simply multiply the number of molecules by the number of chlorine atoms in each molecule. Therefore, 23 molecules of PCl₅ contain a total of 115 chlorine atoms.
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Potentially harmful reactive oxygen species produced in mitochondria are activated by a set of protective enzymes, including superoxide dismutase and glutathione peroxidase. true or false?
The statement, "Potentially harmful reactive oxygen species produced in mitochondria are activated by a set of protective enzymes, including superoxide dismutase and glutathione peroxidase." is: True.
Reactive oxygen species (ROS) are highly reactive molecules that can damage cellular components, including DNA, proteins, and lipids, leading to cell death and contributing to the development of various diseases.
Mitochondria are a major source of ROS production in the cell. However, the cell has a set of protective enzymes, including superoxide dismutase and glutathione peroxidase, that work to neutralize ROS and prevent damage.
Superoxide dismutase converts the superoxide anion into hydrogen peroxide, which is then converted into water and oxygen by glutathione peroxidase. Glutathione peroxidase also converts lipid peroxides into less reactive molecules.
These enzymes act as a defense system against ROS, keeping their levels in check and protecting the cell from damage. However, if ROS levels become too high, the protective enzymes may become overwhelmed, leading to oxidative stress and cellular damage.
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Q. Sara took some ice in a beaker and heated it. She recorded the changes in temperature using a
thermometer and had the following observations:
Time (in min.). Temp. (in C)
0 .-3
1 .-1
2 .0
3 .0
4 .5
5 .8
6 .12
7 .15
8 .19
10 .22
15 .30
20 .50
25 .73
30 .100
35 .100
Based on the above observations, answer the following questions:
a. State the change observed between 2-3 minutes and name the process involved.
b. The temperature remains constant between 30-35 min, what could be the reason for this? Name the heat involved in this process and define it.
"If you found my answer helpful and informative, I kindly request you to consider marking it as the best answer by giving it a brainlist. Your recognition would be greatly appreciated!"
Based on the observations you provided:
a. Between 2-3 minutes, the temperature changed from -1°C to 0°C. This change is due to the process of melting, where the ice changes from a solid to a liquid state.
b. The temperature remains constant between 30-35 minutes because all the water has been converted into steam and the heat supplied is being used as latent heat of vaporization. Latent heat of vaporization is the heat energy required to change a substance from a liquid to a gaseous state at its boiling point without any change in temperature.
determine the halflife of a radionuclide if after 8.4 days the fraction of undecayeda. 1/8b. 1/128c. 1/32d. 1/512
a. the half-life of the radionuclide is: t1/2 = ln(2) / λ ≈ 32.5 days
b. the half-life of the radionuclide is: t1/2 = ln(2) / λ ≈ 8.65 days
c. the half-life of the radionuclide is: t1/2 = ln(2) / λ ≈ 16.3 days
d. the half-life of the radionuclide is: t1/2 = ln(2) / λ ≈ 4.1 days
The formula for calculating the half-life of a radionuclide is:
t1/2 = (ln 2) / λ
where t1/2 is the half-life and λ is the decay constant, which can be calculated from the fraction of undecayed material.
a. If the fraction of undecayed material is 1/8, then the fraction of decayed material is 1 - 1/8 = 7/8.
λ = ln(2) / t1/2 = ln(2) / (8.4 days * ln(8)) ≈ 0.0213 per day
7/8 = e^(-λ*t)
t = -ln(7/8) / λ ≈ 18.5 days
Therefore, the half-life of the radionuclide is:
t1/2 = ln(2) / λ ≈ 32.5 days
b. If the fraction of undecayed material is 1/128, then the fraction of decayed material is 1 - 1/128 = 127/128.
λ = ln(2) / t1/2 = ln(2) / (8.4 days * ln(128)) ≈ 0.0801 per day
127/128 = e^(-λ*t)
t = -ln(127/128) / λ ≈ 87.5 days
Therefore, the half-life of the radionuclide is:
t1/2 = ln(2) / λ ≈ 8.65 days
c. If the fraction of undecayed material is 1/32, then the fraction of decayed material is 1 - 1/32 = 31/32.
λ = ln(2) / t1/2 = ln(2) / (8.4 days * ln(32)) ≈ 0.0426 per day
31/32 = e^(-λ*t)
t = -ln(31/32) / λ ≈ 47.4 days
Therefore, the half-life of the radionuclide is:
t1/2 = ln(2) / λ ≈ 16.3 days
d. If the fraction of undecayed material is 1/512, then the fraction of decayed material is 1 - 1/512 = 511/512.
λ = ln(2) / t1/2 = ln(2) / (8.4 days * ln(512)) ≈ 0.169 per day
511/512 = e^(-λ*t)
t = -ln(511/512) / λ ≈ 14.6 days
Therefore, the half-life of the radionuclide is:
t1/2 = ln(2) / λ ≈ 4.1 days
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The correct answer is b. 1/128.
To determine the halflife of a radionuclide, we need to know the fraction of undecayed atoms remaining after a certain period of time. In this case, we are given that after 8.4 days, the fraction of undecayed atoms is 1/128.
The halflife is the amount of time it takes for half of the original amount of a radionuclide to decay. We can use the fraction of undecayed atoms to calculate the halflife as follows:
1/2 = (fraction of undecayed atoms)^(number of halflives)
We can rearrange this equation to solve for the halflife:
number of halflives = log(base 2)(fraction of undecayed atoms)
number of halflives = log(base 2)(1/128)
number of halflives = -7 (rounded to the nearest whole number)
Therefore, the halflife of the radionuclide is 8.4 days divided by 7 halflives, which is approximately 1.2 days.
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an automobile engine provides 621 joules of work to push the pistons and generates 2150 joules of heat that must be carried away by the cooling system.
Calculate the change in the internal energy of the engine.
The change in internal energy of the engine is 1529 joules
An automobile engine's internal energy can be analyzed using the first law of thermodynamics, which states that the change in internal energy (∆U) of a system is equal to the heat (Q) added to the system minus the work (W) done by the system: ∆U = Q - W.
In this case, the engine generates 2150 Joules of heat (Q) and provides 621 Joules of work (W) to push the pistons. Therefore, we can use the formula to calculate the change in internal energy:
∆U = Q - W
∆U = 2150 J - 621 J
∆U = 1529 J
The change in the internal energy of the engine is 1529 Joules. This result indicates that the internal energy of the engine has increased. The heat generated is greater than the work done by the engine to push the pistons. The cooling system's role is to dissipate this excess heat to maintain the engine's temperature within a safe operating range, preventing overheating and potential damage to the engine components.
In summary, using the first law of thermodynamics, we calculated the change in internal energy of the engine to be 1529 Joules. This highlights the importance of the cooling system in removing excess heat generated by the engine during operation.
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when the following equation is balanced properly under acidic conditions, what are the coefficients of the species shown? cr2o72- mn2 cr3 mno4-
To balance the given equation properly under acidic conditions, we need to consider the oxidation states of the elements involved and apply the appropriate coefficients.
The balanced equation for the reaction between dichromate ions (Cr2O72-) and manganese(II) ions (Mn2+) to form trivalent chromium ions (Cr3+) and permanganate ions (MnO4-) is:
Cr2O72- + Mn2+ -> Cr3+ + MnO4-
To balance the equation, we'll follow these steps:
Balance the least abundant element first. In this case, we have two chromium (Cr) atoms on the left side and one on the right side. Therefore, we need to balance the chromium atoms last.
Balance oxygen (O) by adding H2O molecules as needed. In the reactants, there are seven oxygen atoms in Cr2O72- and four in MnO4-, while in the products, there are four in Cr3+. To balance oxygen, we add three H2O molecules on the reactant side:
Cr2O72- + Mn2+ -> Cr3+ + MnO4- + 3H2O
Balance hydrogen (H) by adding H+ ions as needed. In the reactants, there are no hydrogen atoms, while in the products, there are six in the H2O molecules. Therefore, we need to balance hydrogen by adding six H+ ions on the reactant side:
Cr2O72- + Mn2+ + 14H+ -> Cr3+ + MnO4- + 3H2O
Balance the charge by adding electrons (e-) as needed. In this case, the charges are already balanced.
Now, the balanced equation under acidic conditions is:
Cr2O72- + 8H+ + Mn2+ -> 2Cr3+ + MnO4- + 3H2O
The coefficients of the species are:
Cr2O72-: 1
H+: 8
Mn2+: 1
Cr3+: 2
MnO4-: 1
H2O: 3
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Dinitrogen pentoxide (N2O5) decomposes via a first-order reaction into N2O4 and O2 . 225()→224()+2() The rate constant (k) for this reaction at 45 °C is 6.22 x 10^-4s-1.a. What is the half-life for this reaction?b. If the initial concentration of N2O5is 0.100 M, how long will it take for the concentration of N2O5 to drop to 0.0010M?c. If the initial concentration of N2O5is 0.500 M, what will the concentration of N2O5be after 2.00 hours?d. If the initial concentration of N2O5is 0.445 M, what will the concentration of O2be after exactly 15 minutes?
Dinitrogen pentoxide (N2O5) decomposes via a first-order reaction into N2O4 and O2. This means that the rate of the reaction is directly proportional to the concentration of N2O5.
a. The half-life of a first-order reaction is given by the formula t1/2 = ln(2)/k, where k is the rate constant. Plugging in the given value of k, we get t1/2 = ln(2)/(6.22 x 10^-4 s^-1) = 1117 seconds.
b. To solve for the time it takes for the concentration of N2O5 to drop to 0.0010 M, we can use the first-order integrated rate law equation: ln[N2O5]t/[N2O5]0 = -kt. Plugging in the given values, we get ln(0.0010 M)/0.100 M = -(6.22 x 10^-4 s^-1)t. Solving for t gives us t = 5846 seconds, or 97.4 minutes.
c. Again using the first-order integrated rate law equation, we can solve for the concentration of N2O5 after 2.00 hours (7200 seconds): ln[N2O5]t/[N2O5]0 = -kt. Plugging in the given values and solving for [N2O5]t, we get [N2O5]t = [N2O5]0 e^(-kt) = 0.500 M e^(-6.22 x 10^-4 s^-1 x 7200 s) = 0.190 M.
d. This time we need to solve for the concentration of O2 after 15 minutes (900 seconds). First we can solve for the concentration of N2O5 after 15 minutes: ln[N2O5]t/[N2O5]0 = -kt, so [N2O5]t = [N2O5]0 e^(-kt) = 0.445 M e^(-6.22 x 10^-4 s^-1 x 900 s) = 0.265 M. Now we can use the stoichiometry of the reaction to find the concentration of O2: 2 mol O2/1 mol N2O5, so [O2] = 2 x ([N2O5]0 - [N2O5]t) = 2 x (0.100 M - 0.265 M) = -0.330 M. Since we can't have a negative concentration, the answer is 0 M - all the N2O5 has been used up and all the O2 has been produced.
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if the gew of elemental sulfur is 16.0300 grams, what is the approximate gew of the metal used in the experiment?
The approximate GEW of the metal used in the experiment is 19.4957 grams.
Step 1: Initial crucible weight = 23.0302 grams.
Step 2: Combined weight of crucible and unknown metal = 28.0423 grams.
Weight of the unknown metal = Combined weight - Initial crucible weight
Weight of the unknown metal = 28.0423 g - 23.0302 g
Weight of the unknown metal = 5.0121 grams
Step 3: Sulfur is added, and the crucible with its contents is heated. Excess sulfur is vaporized.
Step 4: Combined weight of crucible and metal sulfide = 34.6023 grams.
Weight of the metal sulfide = Combined weight - Initial crucible weight
Weight of the metal sulfide = 34.6023 g - 23.0302 g
Weight of the metal sulfide = 11.5721 grams
To find the approximate gram equivalent weight (GEW) of the metal, we need to determine the weight of sulfur in the metal sulfide. Since the GEW of sulfur is 16.0300 grams and it combines with 8.0000 grams of oxygen, we can calculate the grams of sulfur in the metal sulfide:
Grams of sulfur = Weight of metal sulfide - Weight of unknown metal
Grams of sulfur = 11.5721 g - 5.0121 g
Grams of sulfur = 6.5600 grams
Now, we can set up a proportion to find the approximate GEW of the metal:
Grams of sulfur / Grams of oxygen = GEW of sulfur / GEW of metal
Plugging in the values:
6.5600 g / 8.0000 g = 16.0300 g / GEW of metal
Solving for the GEW of metal:
GEW of metal = (8.0000 g x 16.0300 g) / 6.5600 g
GEW of metal ≈ 19.4957 grams
The correct question is:
An early development in chemistry was the verification of the Law of Definite Proportions. It was recognized that all binary compounds could be defined as a simple weight ratio between the constituent elements. The amount of an element could be expressed in the gram equivalent weight (GEW), the amount of an element that combines with 8.0000 grams of oxygen. Unlike atomic weight, the gram equivalent weight of an element can be found by chemical analysis of one of its binary compounds.
Elemental sulfur reacts readily with metals to form binary metal sulfides, and was used in the following procedure to help a student determine the GEW of an unknown metal. The procedure consisted of four steps:
Step 1
A porcelain crucible is cleaned with 6 M nitric acid and heated gently. After rinsing and drying, the crucible is heated with a Bunsen burner until the base has a deep red glow. The crucible is allowed to cool to room temperature and then weighed. The initial crucible weight is 23.0302 grams.
Step 2
A sample of the unknown metal is placed in the crucible and they are weighed together. The combined weight is 28.0423 grams.
Step 3
Sulfur is then added, and the crucible with its contents are heated vigorously for 30 minutes. Excess sulfur is vaporized in this step.
Step 4
The crucible was allowed to cool to room temperature and then weighed. The combined crucible-metal sulfide weight is 34.6023 grams.
Question :
If the GEW of elemental sulfur is 16.0300 grams, what is the approximate GEW of the metal used in the experiment?
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the ksp of calcium hydroxide, ca(oh)2, is 1.3 × 10–6. calculate the molar solubility of calcium hydroxide. give the answer is 2 sig. figs
When the Ksp of calcium hydroxide, Ca(OH)₂, is 1.3 × 10⁻⁶ , the molar solubility of calcium hydroxide is approximately 0.010 M.
To calculate the molar solubility of calcium hydroxide,
At first we need to use the solubility product constant (Ksp) for this compound. The Ksp for calcium hydroxide Ca(OH)₂ is given as 1.3 ×10⁻⁴.
The Ksp expression for calcium hydroxide is:
Ksp = [Ca²⁺][OH⁻]²
where, [Ca²⁺] and [OH⁻] are the concentrations of calcium ions and hydroxide ions in the solution, respectively.
Since calcium hydroxide dissolves in water to form [Ca²⁺] and [OH⁻] ions, the molar solubility of calcium hydroxide (S) can be expressed as:
S = [Ca²⁺]= [OH⁻]
Therefore, we can rewrite the Ksp expression as:
Ksp = S × S⁻² = S⁻³
Rearranging this equation gives:
S = ∛Ksp
Substituting the given value of Ksp, we get:
S =∛ 1.3 ×10⁻⁴
S= 0.010 M (approximately)
Therefore, the molar solubility of calcium hydroxide is approximately 0.010 M.
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write the empirical formula of at least four binary ionic compounds that could be formed from the following ions:mg2 ,fe2 ,f-,s2-
The empirical formula of Magnesium Fluoride is; MgF₂, Iron(II) Sulfide is FeS, Magnesium Sulfide will be MgS, and Iron(II) Fluoride is FeF₂ for four binary ionic compounds that can be formed using the given ions.
To determine the empirical formula of binary ionic compounds, we need to combine the cation (positive ion) with the anion (negative ion) in the lowest whole number ratio that results in a neutral compound. Here are four examples using the given ions;
Magnesium Fluoride;
Cation; Mg²⁺
Anion; F⁻
To achieve a neutral compound, we need two fluoride ions to balance the charge of one magnesium ion.
Empirical Formula; MgF₂
Iron(II) Sulfide;
Cation; Fe²⁺
Anion; S²⁻
To balance the charges, we need one iron ion to combine with one sulfide ion.
Empirical Formula: FeS
Magnesium Sulfide;
Cation; Mg²⁺
Anion; S²⁻
To achieve a neutral compound, we need one magnesium ion to combine with one sulfide ion.
Empirical Formula: MgS
Iron(II) Fluoride;
Cation; Fe²⁺
Anion; F⁻
To balance the charges, we need two fluoride ions to combine with one iron ion.
Empirical Formula; FeF₂
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All of the following are the properties of metal except: a) Solid
b) Ductile
c) Malleable
d) Non Conducting
The exception of the properties of metal is "Non-Conducting." The correct answer is option d.
Metals are known to be good conductors of electricity and heat due to the presence of free electrons in their crystal lattice structure. These electrons can move freely throughout the metal, allowing for easy flow of electricity and heat. Additionally, metals are usually solid at room temperature, with a few exceptions such as mercury. They are also known for their malleability, which means they can be easily shaped or bent without breaking.
However, non-metallic materials such as plastics, ceramics, and glass do not possess these properties and are usually poor conductors of electricity and heat. In summary, while metals have a variety of properties that make them unique, being non-conducting is not one of them.
Therefore, the correct option is D.
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Solid." Metals are solid at room temperature in their elemental form, but some metals can be liquid or gaseous at high temperatures or under specific conditions.
Metals are characterized by their luster, ductility, malleability, high thermal and electrical conductivity, and are typically solid at room temperature. These properties are due to the unique arrangement of their valence electrons, which allows for a free flow of electrons within the metal lattice structure. While most metals are solid at room temperature, there are exceptions. For example, mercury is a liquid metal at room temperature, and some metals like cesium and gallium can be liquid or become liquid at slightly elevated temperatures. In summary, while being solid at room temperature is a common property of metals, it is not a defining characteristic.
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calculate the molar mass for mg(clo4)2 a. 223.21 g/mol b. 123.76 g/mol c. 119.52 g/mol d. 247.52 g/mol e. 75.76 g/mol
247.52 g/mol is the right answer, which is d. Finding the atomic masses of each element in the combination and multiplying them by the number of atoms present will allow us to get the molar mass of Mg(ClO4)2.
Magnesium's atomic mass is 24.31 g/mol, chlorine's atomic mass is 35.45 g/mol, and oxygen's atomic mass is 16.00 g/mol.
Since there are two ClO4- ions in the combination, we must double the atomic masses of Cl and O by 2 and 8, respectively.
Molar mass is equal to 24.31 g/mol plus 2.35 g/mol plus 8.16 g/mol.
Molar mass is equal to 24.31 g/mol plus 2 (35.45 g/mol plus 128.0 g/mol).
Molar mass is equal to 24.31 g/mol plus 2 (163.45 g/mol)
Molar mass is equal to 24.31 g/mol and 326.90 g/mol.
351.21 g/mol is the molar mass.
The presence of two ClO4- ions in the molecule must be taken into consideration, though. Therefore, we must multiply the determined molar mass by 2.
Final molar mass: 351.21 g/mol times two.
247.52 g/mol is the final molar mass.
Therefore, d. 247.52 g/mol is the right response.
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a is made up of two unshared electrons and is shown as two dots in a lewis structure is called
A Lewis structure is a diagrammatic representation that illustrates the arrangement of atoms, bonds, and lone pairs in a molecule. It is based on the concept of valence electrons.
In the Lewis structure, also known as the Lewis dot structure, the symbol A represents an element. Each dot in the structure represents a valence electron of the element. Valence electrons are the outermost electrons in an atom and are involved in chemical bonding.
In some cases, an element may have two unshared electrons, which means they are not involved in bonding with other atoms. These unshared electrons are depicted in the Lewis structure as two dots placed next to the element symbol A.
The presence of two unshared electrons can impact the reactivity and chemical behavior of the element, as these electrons are relatively more available for forming bonds or participating in chemical reactions. By representing the two unshared electrons with two dots, the Lewis structure provides a visual representation of the electron configuration of element A.
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The experiment states that a distillation should never be continued until the distilling flask is dry. Does dry mean 'no water present' as when using a drying agent on an organic solution? explain
Main Answer: In the context of distillation, the term "dry" does not mean "no water present." Instead, it means that the distilling flask should not be allowed to become completely empty or run dry during the distillation process.
Supporting Answer: During a distillation, a liquid mixture is heated in the distilling flask, causing it to evaporate and rise up into the condenser, where it is cooled and condensed back into a liquid. If the distilling flask is allowed to become completely empty or run dry, it can cause the temperature of the flask to rise rapidly, potentially leading to overheating, thermal decomposition, or even a fire.
Therefore, it is important to monitor the level of liquid in the distilling flask and stop the distillation before the flask becomes completely empty. The remaining liquid can then be discarded or used for further analysis.
In contrast, when using a drying agent on an organic solution, the goal is to remove any remaining water molecules from the solution to improve its purity or to prepare it for a subsequent reaction. In this case, the term "dry" does mean "no water present" because the drying agent is designed to absorb or remove all water molecules from the solution.
Therefore, in the context of distillation, "dry" means not allowing the distilling flask to become completely empty or run dry, while in the context of using a drying agent on an organic solution, "dry" means removing all water molecules from the solution.
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Calculate the equilibrium constant at 25 ∘C for the reaction
Co(s) + 2Ag+(aq) → Co2+(aq) + 2Ag(s)
Standard Reduction Potentials at 25 ∘C
Co2+(aq)+2e−→Co(s) E∘= −0.28 V
Ag+(aq)+e−→Ag(s) E∘= 0.80 V
Express your answer using two significant figures.
K = ?
The equilibrium constant K for the given reaction at 25°C is approximately 2.5 × 10²² with two significant figures.
To calculate the equilibrium constant (K) for the reaction Co(s) + 2Ag⁺(aq) → Co₂⁺(aq) + 2Ag(s) at 25°C, we first determine the standard cell potential (E°) using the given standard reduction potentials.
E°cell = E°cathode - E°anode Since Ag⁺ is being reduced and Co is being oxidized, the equation becomes:
E°cell = 0.80 V - (-0.28 V) = 1.08 V
Next, we use the Nernst equation to find the relationship between E°cell and K:
E°cell = (RT/nF) K R = 8.314 J/(mol K)
T = 298 K (25°C)
n = 2 moles of electrons
F = 96485 C/mol
1.08 V = ((8.314 J/(mol K)) × 298 K) / (2 × 96485 C/mol) × ln K
Solving for K, we get the equilibrium constant:
K ≈ 2.5 × 10²²
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wWhen borax is dissolved in water, do you expect the standard entropy of the system to increase or decrease?
When borax is dissolved in water, you can expect the standard entropy of the system to increase.
The dissolution process involves breaking the ionic bonds in the solid borax and forming new interactions with the water molecules. During this process,
the solid borax structure breaks apart, and the individual ions become surrounded by water molecules, leading to an increased number of possible arrangements and positions for the particles.
Entropy is a measure of the randomness or disorder of a system, and as borax dissolves in water, the system becomes more disordered.
The reason for this increase in disorder is that the individual ions are no longer in a fixed, crystalline lattice structure and are now free to move and interact with the water molecules in various ways.
As the number of possible arrangements and positions for the particles increases, the entropy of the system increases.
In summary, when borax is dissolved in water, the standard entropy of the system increases due to the breaking of the ionic bonds in the solid borax and the formation of new interactions with the water molecules.
This leads to an increase in the randomness and disorder of the system as the individual ions become more mobile and have more possible arrangements and positions.
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A body system is a group of organs that work together to keep the organism alive. How does the cardiovascular system help to keep an organism alive?
A. The Cardiovascular system takes in oxygen and releases carbon dioxide
B. The cardiovascular system helps the organism absorb nutrients from its environment.
C. The cardiovascular system helps the organism respond to its environment.
D. The cardiovascular system carries oxygen to the organism's cells.
The correct answer is D. The cardiovascular system carries oxygen to the organism's cells.
The cardiovascular system, also known as the circulatory system, is responsible for circulating blood throughout the body. The main function of the cardiovascular system is to deliver oxygen and nutrients to the body's cells and remove waste products like carbon dioxide.
The heart, blood vessels, and blood are the three main components of the cardiovascular system.
The heart pumps blood throughout the body, while blood vessels (arteries, veins, and capillaries) carry the blood to and from different parts of the body. Oxygen is carried by red blood cells in the blood and is delivered to the body's cells through the capillaries.
Without oxygen, cells cannot produce energy and carry out their essential functions, which can lead to cell death and ultimately, organ failure. Therefore, the cardiovascular system is critical for an organism's survival by ensuring that its cells receive the necessary oxygen and nutrients to carry out their functions.
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since this reaction takes place in the absence of the enzyme, what is the physiological advantage in having such enzyme in the blood? [hint: find what the turnover number is for this enzyme.]
The physiological advantage of having an enzyme in the blood is that it can increase the speed and efficiency of the reaction, increasing the turnover number , allowing for proper regulation of metabolic processes in the body.
The turnover number is defined as the maximum number of substrate molecules that an enzyme can convert to product per unit time, when the enzyme is fully saturated with substrate. In the absence of an enzyme, the reaction rate is much slower than when the enzyme is present. Therefore, the physiological advantage of having such an enzyme in the blood is that it speeds up the reaction, increasing the turnover number. This means that the enzyme can catalyze the reaction more efficiently and quickly than in its absence.
In biological systems, enzymes are necessary to facilitate and regulate metabolic processes that occur in the body. Without enzymes, many reactions would occur too slowly or not at all, leading to a buildup of substrates and potentially harmful byproducts. In the case of the reaction mentioned, the enzyme likely plays a role in maintaining proper levels of substrates and products, which is crucial for maintaining the health and function of cells and tissues.
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A metal which is expensive and used to make ornaments.
Answer:
Few metals among them:
Rhodium PlatinumGoldSilverExplanation:
Some metals that are expensive and used to make ornaments are:
Rhodium:
Rhodium is a rare, silvery-white, hard, corrosion-resistant transition metal. Rhodium is a noble metal and a member of the platinum group. It is one of the rarest and most valuable precious metals.Platinum
Platinum is a rare, silvery-white metal that is very durable and resistant to corrosion.It is often used in jewelry because of its beauty and longevity.Platinum is also used in a variety of other applications, such as dentistry and electronics.Gold
Gold is a yellow metal that is also very durable and resistant to corrosion.It is often used in jewelry because of its beauty and value.Gold is also used in a variety of other applications, such as dentistry and electronics.Silver
Silver is a white metal that is less durable than gold or platinum, but it is still a popular choice for jewelry.Silver is also used in a variety of other applications, such as tableware and photography.These are just a few of the many metals that are used to make ornaments. The specific metal that is used will depend on the desired look and durability of the ornament.
What is the mass of 9. 6x10²³ formula units of ammonium sulfide, (NH₄)₂S?
The formula unit of ammonium sulfide is (NH₄)₂S. Its molar mass is 68.142g/mol. The number moles in it are given by dividing the given weight of the substance by its molar mass. The mass of 9.6x10²³ formula units of ammonium sulfide is 108.36
To find out the mass of 9.6 x 10²³ formula units of ammonium sulfide, we first have to calculate the molar mass of ammonium sulfide, which can be calculated as follows: NH₄ = 4(1) + 1(14) = 18g/mol, S = 1(32) = 32g/mol. So, the molar mass of (NH₄)₂S = 2(18) + 32 = 68g/mol. Next, we will calculate the number of moles of (NH₄)₂S present in 9.6 x 10²³ formula units of ammonium sulfide. Moles = number of formula units/Avogadro's number, Moles = 9.6 x 10²³/6.022 x 10²³Moles = 1.595 mol. Finally, we will calculate the mass of 9.6 x 10²³ formula units of ammonium sulfide. Mass = number of moles x molar mass. Mass = 1.595 mol x 68g/molMass = 108.36 g. Therefore, the mass of 9.6 x 10²³ formula units of ammonium sulfide is 108.36 g.
The mass of 9.6 x 10²³ formula units of ammonium sulfide is 108.36 g. The formula unit of ammonium sulfide is (NH₄)₂S. To determine the mass, we first calculated the molar mass, then the number of moles of ammonium sulfide present, and finally the mass of the formula units.
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how many and bonds are in this molecule? the molecule n c c h o. note that there is a nitrogen carbon triple bond and a carbon oxygen double bond.
There are two bonds in the nitrogen-carbon triple bond and one bond in the carbon-oxygen double bond.
The molecule NCCCHO contains a nitrogen-carbon triple bond and a carbon-oxygen double bond. The nitrogen-carbon triple bond consists of two pi bonds and one sigma bond, for a total of three bonds. The carbon-oxygen double bond consists of one pi bond and one sigma bond, for a total of two bonds. Therefore, in total, there are five bonds in the molecule. The nitrogen-carbon triple bond is a strong bond due to the overlap of three hybridized orbitals, resulting in a shorter bond length and higher bond energy. The carbon-oxygen double bond is also strong, but less so than the nitrogen-carbon triple bond. The presence of these bonds affects the molecule's properties, such as its reactivity and polarity.
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calculate the vapor pressure in a sealed flask containing 55.0 g of ethylene glycol, c2h6o2, dissolved in 155 g of water at 25.0°c. the vapor pressure of pure water at 25.0°c is 23.8 torr.
The vapor pressure in the flask is 21.6 torr. When a non-volatile solute is dissolved in a solvent, the vapor pressure of the solution is less than the vapor pressure of the pure solvent.
This is known as Raoult's law. The vapor pressure of a solution can be calculated using the following equation:
P =[tex]X_{solvent}[/tex] * [tex]P^{o}_{solvent}[/tex]
where P is the vapor pressure of the solution, [tex]X_{solvent}[/tex] is the mole fraction of the solvent, and [tex]P^{o}_{solvent}[/tex] is the vapor pressure of the pure solvent.
In this case, we need to calculate the mole fraction of water in the solution: moles of water = mass of water / molar mass of water = 155 g / 18.02 g/mol = 8.60 mol, moles of ethylene glycol = mass of ethylene glycol / molar mass of ethylene glycol = 55.0 g / 62.07 g/mol = 0.887 mol
Total moles of solute and solvent = 8.60 + 0.887 = 9.487 mol
Mole fraction of water = 8.60 / 9.487 = 0.906
Mole fraction of ethylene glycol = 0.094
The vapor pressure of water at 25°C is 23.8 torr. [tex]P_{water}[/tex] = [tex]X_{water}[/tex] * [tex]P^{o}_{water}[/tex] = 0.906 * 23.8 torr = 21.6 torr
Therefore, the vapor pressure in the flask is 21.6 torr.
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assume that you are provided with an 18 cm fractionating column having an hetp of 6 cm to distill a mixture of 84 % toluene and 16 % acetone. what would be the composition of toluene in the first drop of distillate?
The composition of the first drop of distillate would be 74% toluene and 26% acetone.
The first drop of distillate from an 18 cm fractionating column with a heat input of 6 cm can be calculated using the vapor-liquid equilibrium (VLE) data for toluene and acetone.
First, we need to find the vapor pressure of toluene at the boiling point of acetone (179.8 °C). The vapor pressure of a liquid is inversely proportional to its temperature, so we can use the vapor pressure of acetone at 179.8 °C as the vapor pressure of toluene at that temperature.
Next, we can use the VLE data to find the composition of the vapor and liquid phases at a given temperature and pressure. We can plot the vapor-liquid equilibrium data for toluene and acetone on a P-h diagram, where P is the pressure and h is the enthalpy. The composition of the vapor and liquid phases can be found at any point on the diagram.
To find the composition of the first drop of distillate, we need to assume that the column is initially filled with liquid toluene and that the first drop of distillate is collected when the vapor phase is saturated with toluene. This occurs at a point on the P-h diagram where the liquid and vapor phases are completely separated.
We can use the vapor-liquid equilibrium data to find the composition of the vapor phase at this point. Since the heat input is 6 cm, we can use the enthalpy of vaporization of toluene to find the composition of the vapor phase. The enthalpy of vaporization of toluene is approximately 81 kJ/kg.
We can then use the P-h diagram to find the composition of the liquid phase at this point. Since the heat input is 6 cm, we can use the enthalpy of vaporization of acetone to find the composition of the liquid phase. The enthalpy of vaporization of acetone is approximately 55 kJ/kg.
The composition of the first drop of distillate can then be calculated by subtracting the composition of the liquid phase from the composition of the vapor phase.
Therefore, the composition of the first drop of distillate can be calculated as follows:
Toluene in first drop = 1 - [(1 - 0.81) - (1 - 0.55)]
Toluene in first drop = 1 - 0.26
Toluene in first drop = 0.74
Therefore, the composition of the first drop of distillate would be 74% toluene and 26% acetone.
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1. calculate the molar mass k2c2o4•h2o, cacl2•2h2o, and the cac2o4 product. (hint: include each h2o)
The molar mass of a compound is the sum of the molar masses of all the atoms in the compound. To calculate the molar mass of a hydrate (a compound that contains water molecules), we need to add the molar mass of the anhydrous (water-free) compound and the molar mass of the water molecules.
1. Molar mass of K2C2O4•H2O:
- Molar mass of K: 39.10 g/mol
- Molar mass of C2O4: 88.02 g/mol
- Molar mass of H2O: 18.02 g/mol
- Total molar mass: 39.10 g/mol × 2 + 88.02 g/mol × 1 + 18.02 g/mol × 1 = 246.26 g/mol
Therefore, the molar mass of K2C2O4•H2O is 246.26 g/mol.
2. Molar mass of CaCl2•2H2O:
- Molar mass of Ca: 40.08 g/mol
- Molar mass of Cl2: 70.90 g/mol
- Molar mass of H2O: 18.02 g/mol
- Total molar mass: 40.08 g/mol × 1 + 70.90 g/mol × 2 + 18.02 g/mol × 2 = 147.02 g/mol
Therefore, the molar mass of CaCl2•2H2O is 147.02 g/mol.
3. Molar mass of CaC2O4:
- Molar mass of Ca: 40.08 g/mol
- Molar mass of C2O4: 88.02 g/mol
- Total molar mass: 40.08 g/mol × 1 + 88.02 g/mol × 1 = 128.10 g/mol
Therefore, the molar mass of CaC2O4 is 128.10 g/mol.
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Aluminum Hydroxide reaction with Sulfuric Acid to form Aluminum sulfate and water. If 32. 5 grams of Aluminum
Hydroxide and 19. 5 grams of Sulfuric acid are used for the formation of Aluminum sulfate, which reactant is the Limiting
Reagent?
Sulfuric acid produces less amount of Aluminum Sulfate (22.5 g) compared to Aluminum Hydroxide (35.6 g), it is the limiting reagent. Therefore, sulfuric acid is the limiting reagent in the given reaction.
Limiting reagent is the reactant that is completely consumed and determines the amount of product formed. The reactant that is not completely used up is the excess reagent. The balanced chemical equation of the reaction between aluminum hydroxide and sulfuric acid to form aluminum sulfate and water is given as follows:2Al(OH)3 + 3H2SO4 → Al2(SO4)3 + 6H2OTo determine which reactant is the limiting reagent, we need to calculate the amount of product formed by using both reactants and compare the values.
Using the given masses, we can calculate the number of moles of each reactant as follows:
Number of moles of Aluminum Hydroxide = 32.5 g / (78.0 g/mol) = 0.4167 mol
Number of moles of Sulfuric acid = 19.5 g / (98.0 g/mol) = 0.1985 mol
Now, we need to determine which reactant produces less amount of product by calculating the amount of product formed by each reactant.
Let's consider Aluminum Hydroxide as the first reactant.
Number of moles of Aluminum Hydroxide = 0.4167 mol
According to the balanced chemical equation, 2 moles of Aluminum Hydroxide produces 1 mole of Aluminum Sulfate.
Amount of Aluminum Sulfate produced = (0.4167 mol / 2 mol) x (342.2 g/mol) = 35.6 g
Now, consider Sulfuric acid as the first reactant.
Number of moles of Sulfuric acid = 0.1985 molAccording to the balanced chemical equation, 3 moles of Sulfuric acid produces 1 mole of Aluminum Sulfate.
Amount of Aluminum Sulfate produced = (0.1985 mol / 3 mol) x (342.2 g/mol) = 22.5 g
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What element is being oxidized in the following redox reaction? Ni 2+(aq) + NH4 + (aq) → Ni(s) + NO3-(aq) N H O Ni
In the given redox reaction, Ni2+(aq) + NH4+(aq) → Ni(s) + NO3-(aq), the element being oxidized is nitrogen (N) .
In the given redox reaction, nickel (Ni) is being oxidized. This can be identified by the fact that the oxidation state of Ni changes from +2 in the Ni2+ ion to 0 in the solid Ni. This means that Ni is losing electrons and becoming more positive, which is characteristic of oxidation in a redox reaction. The ammonium ion (NH4+) is being reduced because it is gaining electrons and its oxidation state is changing from +1 to 0 in the formation of solid Ni. Overall, this reaction is a combination of oxidation and reduction processes, which is why it is called a redox reaction.
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